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Helen C. Kurtz Professor Emeritus |
| (614) 688-4113 zakin.1@osu.edu |
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| Research Interests |
| Drag Reduction, Heat
Transfer Enhancement, Rheology, and
Microstructures of Surfactant Solutions |
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| Education |
| B.Chem.Eng., Cornell
Univ., 1949
M.S., Columbia Univ., 1950
D.Eng.Sci., Chem.Eng., New York Univ., 1959
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| Honors |
| Japanese Government
Research Award for Foreign Specialist, 2001
Distinguished Visiting Professor, Mexican
Academy of the Sciences and the Mexico-USA
Foundation for Science, 1999
Senior Fulbright Research Fellow and Visiting
Professor, Technion, Israel, 1994-95
Hlavka Medal of Czechoslovakian Academy of
Science, 1992
AIChE Fellow, 1984
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| Faculty
- Jacques L. Zakin |
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Turbulent drag reduction is a striking
phenomenon in which the presence of small
quantities of additive (in some cases a few
ppm) in a carrier fluid can reduce turbulent
pressure losses by up to 90%. Highpolymer
drag-reducing additives have been
successfully used in many crude oil and
finished petroleum product pipelines all
over the world.
While useful in once-through applications
such as pipelines, polymer additives are not
suitable for recirculating flows as they are
susceptible to irreversible (permanent)
mechanical degradation in regions of high
stress. For recirculation flows, additives
which are not sensitive to degradation by
shear or extensional flows are needed or, if
they do degrade, their structures must
recover or repair quickly. Many surfactant
additives can recover from mechanical
degradation in seconds and so are effective
in recirculating flows.
To utilize low-cost energy or waste heat,
closed-loop district heating is used in many
cities in northern Europe, Japan, and the
U.S. to heat homes, businesses, and
factories and to provide hot water.
Alternatively, large chillers can provide
low-temperature water for circulation
through a district cooling system. District
cooling systems are becoming increasingly
important in the U.S. and Japan. The use of
surfactant drag-reducing additives in these
systems conserves fuel and thus reduces
pollutants entering the environment and also
reduces the size of pumps and piping. They
can also increase throughput. Preliminary
field tests have been encouraging.
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My current drag-reduction research is focused
on cationic, zwitterionic, mixed surfactant,
and nonionic surfactant/water and ethylene
glycol/water systems suitable for use at
temperatures to at least 100 C for district
heating systems and from -5 to 15 C for
cooling systems. Understanding the influence
of the chemical structure of the surfactant on
its micellar structure, drag-reducing
efficiency, and temperature range and the
influence of micellar size and shape on
drag-reducing ability will permit tailormaking
useful surfactants for these and other
applications. To this end, rheological
techniques such as normal stress, extensional
viscosity, dynamic viscosity, and flow
birefringence measurements, and NMR, SANS, and
cryogenic transmission electron microscopy (cryo-TEM)
are utilized to characterize surfactants solutions. An
international collaborative research project
sponsored by NEDO (Japan) to develop
surfactant additivies for water/ ethylene
glycol systems effective to -5C is underway.
In studies of the effects of chemical
structure of cationic surfactants and of their
counterions, my students and I have discovered
unusual rheological and microstructure
phenomena. We showed that non-viscoelastic
surfactant solutions which are water-like in
their rheological behavior could be
drag-reducing and that the belief that
thread-like surfactant micelle network
microstructures in the quiescent state are
required for drag reduction is not generally
true. Vesicle systems can be transformed into
dragreducing, thread-like structures under
stress. We have also demonstrated that the
limiting Friction Factor-Reynolds number
drag-reducing asymptote for high polymers
proposed by Virk many years ago is exceeded by
some surfactant systems, and we have offered a
new asymptote for surfactants as well as a new
turbulent mean velocity profile asymptote.
Recent work has focused on developing
techniques to enhance heat transfer in
drag-reducing solutions by temporarily
degrading their microstructures in heat
exchangers while allowing them to recover
downstream.
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